PH and what it means for your plants

Discussion in 'First Time Marijuana Growers' started by joe_fresh, Mar 17, 2010.

  1. #1 joe_fresh, Mar 17, 2010
    Last edited by a moderator: May 15, 2014
     PH and what it means for your Marijuana Plants
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    Hey everyone :wave:

    I consider myself a good grower, i have been growing for more than 10 years and in that time i have learned alot, some from experience and some from research and reading. But one thing I have always said and i stand by it A GOOD GROWER HAS LEARNED, A GREAT GROWER NEVER STOPS LEARNING. with that said i invite you guys to read this article i found on PH and how important it really is, not just ph in your nutrients but ph in your starting water and your growing medium all play a major role in your plants health and its ability to grow at faster rates.

    I take no credit in this I am simply sharing information that I have read and feel its important for all growers to know.

     
    One of the biggest misconceptions in hydroponics growing is that the pH in your nutrient reservoir is the single biggest thing having to do with pH that affects the outcome of your crops.
    Well, it's simply not true. It's actually the pH and alkalinity of three things:


    1. YOUR WATER.
    2. GROWING MEDIUM.


    3. NUTRIENTS.
    Unfortunately, this circle of big bud getting power isn't talked about, and it's responsible for more growers silently losing loads of buds and quality they weren't even aware of. Let me explain...we're going to have to get a little technical here, but not too much. So let's take a journey and uncover the really important points about pH so that we can leverage it to get you bigger yields.

    <span style="color:rgb(0,86,110);">First Things First</span>​

    OK, pH stands for potential hydrogen and is actually a measurement of hydrogen and hydroxide ions, and is measured on a scale from pH 0 to pH 14.0 with pH 7.0 being neutral, aha, so we're interested in those pesky little hydrogen and hydroxide ions. They're the culprits? Yes they are. Here's how.

    When your water, growing medium or nutrient solution is acidic (below a pH of 7.0) it contains more hydrogen ions than hydroxide ions. And when your water, growing medium or nutrient solution is alkaline, also referred to as base or basic (above a pH of 7.0) it contains more hydroxide ions than hydrogen ions.
    And these hydrogen and hydroxide ions interact with each other and perform a balancing act of sorts that determines the pH in your water, growing medium and nutrients.

    <span style="color:rgb(0,86,110);">Don't Sweat It</span>​
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    Wow that's a lot of stuff, but it's important you understand all this because it's one of the keys to you getting bigger and better yields. Anyway, these hydrogen and hydroxide ions are also in the elements that make up our macro and micro nutrients of the nutrient solutions we use to grow our plants with. And because of this the elements that make up our macro and micro nutrients are classified into two distinct groups. One group of elements are called cations and contains more hydrogen ions.

    The other group of elements are called anions and contain more hydroxide ions. Also our growing medium pH is dramatically affected by these cations and anions contained in the macro, micro and secondary nutrient elements we use. Remember this because it's important and we'll be referring back to this in the growing medium and nutrients sections.
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    <span style="color:rgb(0,86,110);">Mastering The Subtleties Of The Balance</span>​
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    The macro, micro and secondary elements that are cations are urea and ammonium (both are forms of nitrogen), potassium, calcium, magnesium, iron zinc, manganese copper and cobalt. And the elements that are anions are nitrates (another form of nitrogen), phosphates (phosphorus) sulfates, carbonates and bicarbonates. This list covers the most common cations and anions. This topic will be covered more in the nutrient section. So what does all this stuff have to do with you getting bigger yields? Well a whole lot. We're almost there. These three things, your water, growing medium and nutrients powerfully form a circle that when kept in balance with each other truly hold the keys to the buried treasure that is commonly overlooked and waiting to be unlocked in a grower's garden. And the best part, it will absolutely give you bigger more consistent and higher quality yields when fully understood and implemented. So let's explore this circle of power a little deeper...
     ​
    Like I mentioned earlier, the most common misconception is that the pH of your nutrients is the most important factor that will drive your plants ability to give you bigger yields. You would think that your biggest concern would be about the pH in your reservoir. This is just not true. You should be more concerned with your water's alkalinity. This is one of the major culprits that will affect your yields. In fact, one of the biggest problems with water is its alkalinity. This is something that must be taken care of if you really want to easily manage the pH of your nutrients and growing medium and get those bigger crops.
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    <span style="color:rgb(0,86,110);">The Simple Truth Of “Alkalinity”</span>​
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    And what is this “alkalinity”, anyway? Your water is not just water. There is a lot of other stuff in it. The alkalinity of water is the concentration of all sorts of ions in it, like calcium, magnesium, sodium, potassium, both come in the forms of carbonates and bicarbonates. And bicarbonates are the worst offenders of the two.
     ​
    Making matters worse, alkalinity insidiously accumulates in your growing medium in a vicious cycle that will cause your growing medium pH to climb faster than a speeding bullet and give you pH stability problems in your reservoir and growing medium, substantially decreasing your yields.
     ​
    When the amount of alkalinity in your source water hasn't been measured and is then used to mix your nutrient solution - even with a properly pH balanced nutrient reservoir - your plants can suffer from a continuous build up of alkalinity that will silently sneak up on you and quickly raise your growing mediums pH, locking out your plants vital elements, and hijacking you from your crops true harvest potential.
     ​
    In fact, farmers who have to irrigate their field crops and have alkalinity in their water supply have to continuously inject different types of acids - depending on what the farmer is trying accomplish with the crop and soil - into their irrigation lines to counter balance their alkalinity. An easy way to think of alkalinity is pH up. Unfortunately a very bad form of pH up. Once alkalinity is neutralized, fertilizer is then injected into the lines.

    Here's something to think about, depending on what crop is being grown, the fertilizer being injected will be balanced with the correct cation to anion ratios for that crop's soil pH requirement. If they need to lower their soil's pH they'll use a fertilizer that has more cations than anions. And if they need to raise the soil's pH they will use a fertilizer with more anions than cations. We'll go over this more in the nutrient section. And then there's the subject of water hardness. Shouldn't you be concerned about that? Well, It's important not to confuse water hardness with the alkalinity of water. These are two different things.
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    <span style="color:rgb(0,86,110);">Here's The Difference:</span>​
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    “Hardness” is the measure of the combined concentration of insoluble calcium and magnesium in the water, not the presence of the carbonates or bicarbonates mentioned earlier. When the amount of alkalinity in your source water hasn't been measured and is then used to mix your nutrient solution - even with a properly pH balanced nutrient reservoir - your plants can suffer from a continuous build up of alkalinity that will silently sneak up on you and quickly raise your growing mediums pH, locking out your plants vital elements, and hijacking you from your crops true harvest potential. Using a water softener to handle the hardness will only displace the calcium and magnesium ions and leave the carbonates and bicarbonates behind, which doesn't change the alkalinity at all. So this is not the thing to do. And a BIG WARNING, using a water softener will add unwanted sodium to your water severely decreasing your yields. If you're using well water it is almost guaranteed you will have alkalinity problems. In fact most municipalities have water that is poor quality and has alkalinity. I have personally seen municipal water that's 900 PPM and chocked full of alkalinity. Here's the thing, if your water is 30 PPM or below you're safe. And I've seen city water that has less than 10 PPM, Vancouver, Canada being one of them. Anything over 30 PPM and you should invest in a reverse osmosis system.​
     ​
    <span style="color:rgb(0,86,110);">Let's Explore How To Measure And Manage All This</span>​
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    So now the question arises, “how do we measure alkalinity?” Well, the way that alkalinity is measured is how much carbonate and bicarbonate is in the water. Alright, so now we have to test the water. But how do we do that? Well, there are several ways to test water alkalinity. One way is with an alkalinity meter (which measures it in PPM) which is quite different than an EC meter. As an aside you can use an EC meter to do a quick check but it is not the same measurement. And the least expensive way to check your alkalinity is with a test kit where you add dilute acid until a color change occurs at a specific pH. Now, you can get a digital meter for about $200 at www. hach.com. But if you want to go easier on the pocketbook, there are kits as cheap as $30 to $40. And you should get one that uses titration which is actually the most accurate method of testing.
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    <span style="color:rgb(0,86,110);">Here's Something Interesting About pH Readings</span>​
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    OK, so that seems simple enough, but now I'm going to add just a little variance into the subject to make it more interesting. Taking pH readings during the light cycle will give you a different result than when you take pH readings at night. The reason for this is, during the dark periods, both microbes and the plants are resting and give off alkaline molecules and the pH tends to go up a bit. During the day the plant and microbes are active and they give off acid molecules which make the pH go down some.
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    If you're running a recirculation system this is important to consider, especially because your tank should be outside your grow room. And you might be taking your readings when your plants are in their dark cycle.
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    Here is one of the biggest secrets the best growers in the world figured out along time ago: if you want a world class crop you have to use really great water. And a very simple way to ensure that is get a reverse osmosis water system. It's an absolute must for bigger yields.
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    <span style="color:rgb(0,86,110);">You May Want To Read That Last Line Again...</span>​
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    Think about it, you spent all that time and hard work building your grow room and in the final hour you skimp on the water, it just doesn't make sense, you really should invest in a reverse osmosis system. They aren't that expensive these day, prices start for under $100. A reverse osmosis system will take the alkalinity out of your water and give you bigger yields. And obviously alkalinity is one of our limiting factors we want to get rid of, isn't it?
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    <span style="color:rgb(0,86,110);">When You Invest In RO Remember These Tips</span>​
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    One word of advice: you should have a tank mounted shut off float valve installed on your R.O water storage tank and nutrient reservoir that shuts off automatically when the tank is full, and you should keep your nutrient tank topped off because, as water level lowers, the pH will be magnified as either acidic or alkaline. You can get one at: www.autotopoff.com/products

    <span style="color:rgb(0,86,110);">One Last Thing About Your Water</span>​
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    Now here is the last thing I will say about the water you use and then we'll take a look at the growing medium. There is one more thing to pay attention to when it comes to your water. The temperature is important as well. Cooler water holds more oxygen as well as affects your pH level, but if it is too cold, it will cause your pH to rise, and if too warm, it will cause it to go down. Here's a little known fact, excessively high water temperatures above 79F or 26 C start to negatively impact your plants ability to absorb macro nutrients. High temperatures also encourage fungal and bacterial diseases, and you don't want that either. In fact, it is best to maintain a nutrient reservoir temperature of 65F or 18C to 69F or 20C. And colder water holds a lot more oxygen.

    And here's another fact, scientists who study our oceans consider warm tropic waters to be the “deserts” of the oceans because they contain way less life than the colder waters of the Arctic and Antarctic oceans, that are teeming with life because of the colder water temperatures holding more oxygen. In the end if you want bigger yields go out and buy a reverse osmosis system it will be some of the best money you'll ever invest in your grow room.All my labs grow rooms use reverse osmosis water. In fact it's so important all Advanced Nutrients products are made with ultra pure zero PPM and zero alkalinity reverse osmosis water.

    <span style="color:rgb(37,65,143);"><span>Your Growing Medium</span></span>​

    <span style="color:rgb(0,86,110);">The Secret Beneath Your Plants</span>​
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    OK, let's explore your growing medium – A lot has been said about measuring pH in the nutrient solution, but where the real money is being won or lost by the buckets full, is in the actual growing medium itself. Your plants roots are actually pH producing “machines” creating either hydrogen ions (pH down) or hydroxide ions (pH up) depending on whether the roots are taking in elements that are mostly cations or anions.
     ​
    Here's why... your plants' root system is actually a pH excreting machine that manufactures and pumps hydrogen ions (pH down) or hydroxide ions (pH up) directly into your growing medium and will directly change the pH of the growing medium depending on the elemental composition of your nutrients make up. And you can imagine how having a thorough understanding of this is going to give you even more control over your plants that will lead to bigger yields, right?
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    <span style="color:rgb(0,86,110);">The Most Important Link In The Chain</span>​
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    Out of the circle of big bud getting power, it's your growing medium that you need to be most concerned about. Because if you want a really great crop, your plants must have an acidic pH growing medium. In most cases your pH will be climbing and your challenge will be to keep your pH from going up.
     ​
    Sure, the water, the growing medium, and the nutrients should all have to work in prefect harmony with each other, but it's the roots in the growing medium that drives the pH chemical reactions that is the most overlooked by growers and it's not your fault it's just most books out there don't go into great depth about it. And naturally this is very important because, the pH in the root zone is going to determine the availability of nutrients and your plants ability to produce world class buds. And we all want to grow kick ass buds, don't we?
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    <span style="color:rgb(0,86,110);">An Important Lesson To Nutrient Company Owners</span>​
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    I have extensively tested the competitors hydroponics nutrients, and unfortunately the vast majority of them don't work with the plants root system to even remotely come close to maintaining a stable or ideal pH in the growing medium. Because they use too much nitrates as there source of nitrogen . Here's the straight goods... and an education for a lot of the nutrient manufacturers out there, to balance a growing mediums pH, nutrient manufacturers must be using the correct balance of cations to anions to guarantee you the right pH in your growing medium.
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    And...One more thing, the right balance of elements (cations to anions) that
    will give you a stable and ideal growing medium pH is different from plant species to
    plant species. And by not being aware and acting on this vitally critical piece of knowledge is exactly like growing with one foot on the gas and the other foot on the brake at the same time.


    <span style="color:rgb(0,86,110);">Why Would Anybody Work Against Themselves Like This?</span>​
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    So why are nutrient companies not building there products with this in mind? Well, I will give you two reasons for that. One is the high expense and the other is the amount of research and knowledge needed to prepare the nutrients for a specific type of plant.
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    I admit it... I go on the forums every once in a while, and it always amazes me when I see people making statements like, “all base nutrients are the same and salts
    are just salts”.

    Think about it... is there a difference in the foods you eat. Are your sources and quality of proteins, carbohydrates and fats you eat, all the same? Absolutely not, some proteins are assimilated and utilized by your body faster and more completely than others.

    And some carbohydrates release quickly and spike your insulin while others are a slow burn and give you sustained energy.

    What about fats? Some are actually good for you like Omega-3 and others will slowly clog your arteries and eventually give you a heart attack. Obviously it all makes a difference. And in the nutrient section we'll take a look at this in depth.
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    <span style="color:rgb(0,86,110);">What's Your Favorite Growing Medium?</span>​
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    Now if you've looked lately, you probably noticed that there is a variety of growing mediums to choose from. You have sphagnum moss – that stuff from bogs. And there is coco coir, the fiber that comes from the coconut's outer husk. And let's not forget about the special mixes and all the other hydroponic growing mediums.

    Now you might want to keep it simple so what I recommend is that you use Sunshine #4 mix. This is a mix that is pretty close to ideal and will save you a lot of work. We'll talk a bit more about that later. You might even choose coco coir since it is also a good growing medium and has a special line of compatible fertilizers. The thing about different hydroponic mediums is that they have varied abilities to maintain and control pH.
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    <span style="color:rgb(0,86,110);">So Let's Take A Closer Look At Them</span>​
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    OK, so we had a look at some growing mediums. Now we'll look at them and a few others in a different perspective. In hydroponics, there are two basic types of growing mediums: those that are pH independent and those that are pH dependent. Let's take a closer look at these mediums differences. Well, each one of them has a certain ability to stabilize or buffer pH, which is another way of saying they have varied abilities to keep the pH from changing on you. This ability is called cation exchange capacity or CEC. In other words, CEC refers to the ability of the medium to absorb and release cations. Remember the cation stuff I mentioned at the beginning of this report? We'll be looking at this a little bit closer now.
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    <span style="color:rgb(0,86,110);">Dependent Vs. Independent</span>​
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    Mediums that are pH dependent have little to no CEC and cannot resist a change in pH and this results in the pH going high or low very rapidly. So, then, mediums that are pH independent have a high CEC, are more buffered and can resist a change in pH for long periods of time. And that's good! That's what you want. As an example your everyday, garden, soil-based medium contains some humus and clay and is pH independent with a high CEC because of the humus and clay. They are great to grow plants in because it is not affected by rapid pH swings.

    <span style="color:rgb(0,86,110);">But Indoor Growers Have To Follow Different Rules</span>​
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    Now, hydroponics is different. Many of its mediums have a low CEC and needs to have the pH continually balanced and monitored. More on this later. Of course, there are some that have a higher CEC and are better buffered than others. For example, coco coir and sphagnum moss have higher CEC capacities. This means they are capable of maintaining a more stable pH level. These are said to be pH independent. Sphagnum actually has eight to ten times the CEC as soil pound for pound, but there are other drawbacks. But not to worry, these could be easily remedied, though no manufacturer has done this yet. You see, Sphagnum doesn't have the bulk density that soil has. After all, it is a moss and is light in weight. But you can add something called calcined clay to solve that problem.
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    <span style="color:rgb(0,86,110);">Calcined Clay</span>​
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    All you need to do is add is 5% – 7% to your sphagnum growing media. And what is calcined clay? Well, this is clay that has been heated to drive out volatile materials. One word of caution though. Make sure you use a low sodium source of calcined clay because you don't want extra sodium in your growing medium.
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    Now what about low CEC growing mediums? Some hydroponic mediums that we use, such as rock wool, expanded clay pellets or perlite, have a low CEC and so they have a hard time stabilizing the pH. We call them pH dependent and, you probably have already guessed by now, you will need to correct the pH more often.
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    How about the Sunshine #4 mix that we mentioned earlier? Actually this is a very, very good medium. When it comes out of bogs, it has a pH of 3.5 to 4. This is actually too low, so dolomite lime is added to it to raise the pH. (We'll talk about adding dolomite a bit later.) This brings the pH of the Sunshine #4 to 5.8 to 6.3 for a 6 week period.
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    <span style="color:rgb(0,86,110);">More About “Sunshine #4” And How It Can Make Your Life A Lot Easier</span>​
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    So what's Sunshine #4 mix made of? It's made of 60% – 70% peat and 30% – 40% perlite. This is the combination you want and gives you excellent aeration which you'll need for great big thick root development. And as hundreds of university studies have conclusively shown the bigger the root system the bigger the yield. And that's what we're after isn't it. BIGGER YIELDS. It also has a starter charge of fertilizer that gives it an NPK ratio of 6-5-11 meaning it has a ratio of 6% nitrogen (N), 5% phosphorous (P) and 11% potassium (K). All you have to do, then, is add a bit more nitrogen to the mix and this would be a near perfect medium for growing your plants. Sunshine #4 also contains a wetting agent (surfactant) to ease surface tension and allow for better initial water penetration to the growing medium.
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    <span style="color:rgb(0,86,110);">Coco Coir (And How To Overcome Its Limitations)</span>​
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    Let's have a look at coco coir. It starts out with a better pH of 5.5. But the problem with this medium is that magnesium and calcium binds to coco and doesn't want to easily release. And that's not good. Your plants need to be able to get to those nutrients.

    Now if you add dolomite lime, as a lot of companies out there will do because dolomite is cheap to use and made up of magnesium and calcium carbonate and a source of alkalinity, that will eventually raise your growing mediums pH and this is not what you want to do. So what do you do? You would solve the problem by adding chelated calcium and magnesium either to the coir or in the base nutrients. Unfortunately, other nutrient companies won't do this because of the very high added expense, but that is exactly what we put in all the base nutrients at Advanced Nutrients. However Advanced Nutrients doesn't make a specific coco nutrient yet. Coco coir also has a lot of potassium so you'll need to use a fertilizer with reduced potassium so you don't end up with potassium toxicity. There is one other thing to be aware of: low quality coconut husks are often soaked in salt water as part of the manufacturing process to break down the husks and quite often not properly flushed by the coir manufacturer overseas. You'll need to make sure that the extra salt is flushed out of your medium with water by either yourself or the manufacturer you're buying it from before usingit.
    <span style="color:rgb(0,86,110);">This Step Is Very Important</span>​
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    Because if you don't, you will have high sodium content in your growing medium and that will severely reduce your yield when using cheaply produced coir, and this problem is more common than you might think. If you're thinking about using coco coir as your growing medium, you're going to find coir still has some inherent problems with it that have not been resolved completely, that's why you'll probably have to use a Cal Mag product when growing with coir. At one point Advanced Nutrients pulled Sensi Cal calcium and magnesium product off the market because we figured if a nutrient was built right you didn't need it. Man, stores started calling and demanded we keep it on the market, so we did. Here's what the hydro store owners told us was happening: Growers growing with coco coir were using Sensi Cal to fix the calcium and magnesium deficiencies caused by the coir they were using. Which of course told us that there hasn't been a correct coco nutrient formula made yet that addresses the needs of the growers using coir growing mediums. So, at some point we will bring out a coco coir nutrient and then later on down the road, a coir growing medium that will be perfectly aligned with each other. We'll be doing the same thing for a sphagnum moss growing medium too. Enough of the commercial.
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    <span style="color:rgb(0,86,110);">Monitoring Your Growing Medium pH</span>​
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    Remember, we talked about monitoring growing medium pH? One of the most overlooked areas by growers is checking their growing medium pH on a regular basis. That is probably the biggest single culprit for yield inconsistencies from crop to crop and it could be costing you a lot of money. Let me explain how this happens. As the roots take in an element, it gives off a positive charge, pH down (hydrogen ion) or a negative charge pH up (hydroxide ion), and depending on the nutrient elements being used, some carry more of the same charges than others. What's more, because of this it affects the pH of the surrounding root area and growing medium. If it's hydrogen ions being excreted, it becomes more acidic, and if it's hydroxide ions, it becomes more alkaline.
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    <span style="color:rgb(0,86,110);"><span style="color:#FF0000;">How To Measure Your Growing Medium pH</span></span>​
    So it's important to monitor the pH levels in your medium as well as your nutrients and the alkalinity of water youare using. So how do you measure your growing medium pH? Basically, there are three ways to do it:
    1. Saturated media extract – you add distilled or de-ionized water to the medium just to the saturation point
    and measure.

    2. Pour-through method – the water is poured through the pot to replace the water that was in there and
    collected.

    3. Squeeze method – the water that already exists in the medium is
    gently squeezed out in a measured amount and pH readings are taken.


    In all three of these, you just use a pH meter or color test to measure the pH. The easiest of the three is the squeeze method. If you are using rock wool, you just take one of the cubes after a feeding and you gently squeeze it.

    Repeat this with at least six different cubes so that you get a couple ounces or 60 milliliters from each cube. After combining and mixing these six extractions together, check the pH. This tells you what the pH is in the growing medium.
    What you're looking for is a pH range of 5.3 to 6.8. In our labs we've extensively tested pH ranges and yields, this is the “sweet spot” for nutrients that are not fully chelated. The range is even wider for fully chelated macro, micro and secondary nutrients. When your growing medium is coco coir or sphagnum moss, you water your medium to the point of being saturated (but not leaking out the bottom) and then take a sample from the bottom 2/3 of your pot where your roots are most actively growing.

    Next...you take the same amount from six different pots and mix them together. Make sure to take the same amount from each pot. Then gently squeeze it and get an extraction from which you will measure the pH. Look I realize that taking samples from grow buckets is a hassle however; it is the most accurate.

    <span style="color:rgb(0,86,110);">There's An Easier Way</span>​
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    A much easier way is to get a pH meter with a metal spike probe and take readings simply by sticking the probe deep down into the growing medium and calculate the average of all six containers. Now, don't take the sample from the top third of the container, here's why. There isn't as much root growing activity at the top of the soil. So use the bottom two thirds of your growing medium to take your pH readings because that is the active zone for root growth. There's another reason for taking the samples near the bottom of your container, and that's because nutrients will tend to crystallize near the top and can precipitate out a little bit and will give you a false reading.

    <span style="color:rgb(0,86,110);">Using pH Meters</span>​
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    So now, we should look at the meters we need to measure the pH. There are so many different pH meters available, but get one that uses dual solution to calibrate your pH meter. It's a good idea to get one that auto adjusts and has ATC (automatic temperature compensation). This will be more expensive but worth it. The cheaper ones are a pain to use while the auto-adjust ones calibrate at a press of a button, which makes it a lot easier. You want to make sure that calibration is done every week. If you're fanatic to detail like I am you'll want to have a pH meter with ATC because as your nutrient solution temperature changes so does the pH of your nutrients when your nutrient temperature gets warmer your pH goes down and when your nutrient temperature gets cooler your nutrient solution pH goes up. Here's an interesting side note, a pH of 7 is considered to be pH neutral, but in fact is only an approximation and is accurate only at 25 C or 77F. A true neutral pH is when the concentration of hydrogen ions (H+) is exactly the same as the concentration of hydroxide ions (OH- ) and those concentrations are effected by temperature so your pH neutral point varies from pH 7.47 at 0C or 32F to pH 6.14 at 100C or 212F.
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    A Good Resource
    If you're looking for really high quality pH measuring instruments and electrodes check them out: www.pulseinstruments.net


    <span style="color:#00566e;"><span style="font-family:'Arial-BoldMT';"><span style="color:#00566e;">B<span style="font-family:tahoma, geneva, sans-serif;">acteria In Your Growing Medium</span></span></span></span>
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    It may surprise you to find out just how much activity is going on under the surface of the growing medium. There is actually a lot going on there including bacterial activity. But before we get into that, we need to say a bit about beneficial bacteria and nitrogen. Plants need nitrogen as an essential element for its survival. There is a process that bacteria is involved in called nitrification.

    <span style="color:rgb(0,86,110);">The Role Of Nitrification</span>​
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    Nitrification is a process where specialized beneficial bacteria in your growing medium take the urea and ammonium from the nutrients and convert them into usable forms. Then the plant roots can absorb it and use it for plant growth and development.
     ​
    Laboratory Grade pH And EC Meters- Here are high end laboratory grade EC, pH meters and probes that cost from several hundred to over a thousand dollars. pH Temperature Chart - Contrary to popular belief a pH of 7.0 is not always neutral, in fact it really depends on the temperature of your nutrient solution as the chart above shows.
    That's why it's critical to make sure you buy a pH meter that compensates for temperature. By the way, an important thing that happens in this process is that these beneficial bacteria then give off an acid molecule which actually lowers your growing mediums pH as well. And that's a good thing. Now, if you have a pH that is too low, nitrification will be inhibited. The same happens when your medium has too low a temperature or there is a lack of oxygen through over-watering. Then the pH goes up and the medium becomes more alkaline. Not good!

    <span style="color:rgb(0,86,110);">Beneficial Microbes Switch Gears At Night</span>​
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    At night beneficial microbes are at rest and respirating, and they give off alkaline molecules instead of acid as they do during the day, and the pH goes up. Some interesting facts, some microbes give off more hydrogen ions (pH down) in a 24 hour period than hydroxide ions (pH up). And some do exactly the reverse. Also make sure that you do not over water your plants, and provide a somewhat warm growing medium (65F or 18C to 75F or 23C) so it will encourage active growth of beneficial microbes. This will help to keep your pH stable, and your growing medium more acidic.
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    <span style="color:rgb(0,86,110);">Making Your Own Growing Medium Mix</span>​
     ​
    Now, you might have decided to make your own media mix. If so, alright. But if you start with pure sphagnum moss, you will need to add at least 30% perlite (between 30 – 40%) so that the sphagnum moss can breathe and aerate properly, allowing the roots to pass through quickly and infuse into your growing medium. When using sphagnum moss you could add 5 to 7% calcined clay to increase the cation exchange capacity (CEC). This would help stabilize the pH in that growing medium. I would not use calcined clay in a recirculating system only in a “one way” feeding program. Of course, if you are new to hydroponics, I would suggest you start by using Sunshine #4 mix, which has very good CEC and is very forgiving. You will get a good crop even if you make a few mistakes.
     ​
    <span style="color:rgb(0,86,110);">Sometimes There's An Unexpected Aspect To “Do-It-Yourself” Mediums You Should Be Aware Of</span>​
     ​
    There is something else that you might run into when mixing your own medium. And that is inconsistent growing medium. The number one cause of pH problems for growers mixing their own mediums is inconsistencies in source materials. When mixing your own growing medium you need to know the sources of your sphagnum moss and lime because they differ in pH from year to year and locations. The only way to be certain you are working with the right pH materials in your medium is to test it frequently. See“Laboratory Registry for the United States and Canada 2nd Edition,” CRC Press (ISBN 1-57444-179-5) to get a comprehensive list of soil-testing laboratories in the United States and Canada.

    <span style="color:rgb(0,86,110);">Adding Limestone</span>​
     ​
    Earlier I mentioned adding limestone or lime. When you have a medium that is too acidic, you have to add something to bring it up into a better range. For example, you will find that sphagnum (pH of 3.5 to 4.0) is very acidic to use as a medium. So you'll want to use limestone to neutralize this acid and raise the pH to a level acceptable for plant growth. The amount needed depends on different factors such as sphagnum sources, types of ingredients, and limestone type. Another thing, when limestone is added to your growing medium, only a fraction of the lime reacts to increase the pH to a stable level in 5 to 10 days after planting. And this is called the reactive fraction.
     ​
    So what happens to the rest that doesn't react? Well, this is called un-reacted or residual limestone, and it affects the long-term buffering capacity of your growing medium. It is the residual limestone that you want to measure regularly in order to test how good your limestone source is. Actually, each limestone source is different, so there is no way to determine the residual fraction except to test it.
     ​
    There is also a variance in the limestone you get depending on what part of the quarry it comes from. You will find a variance in pH with sphagnum moss as well, depending on what part of the bog it is harvested from and what time of year or even what year.

    <span style="color:rgb(0,86,110);">The Three Main Features Of Lime</span>​
     ​
    So when you use sphagnum as your medium, there are three main features of lime that determine how much is needed to raise its pH. These features are limestone type, particle size and hardness.

    Limestone Types
    In dealing with limestone type you actually have two choices:

    1. Calcitic which is straight calcium carbonate.

    2. Dolomite which is a combination of calcium and magnesium carbonate.

    I do not recommend Calcitic limestone as your optimum choice because it releases too fast and usually raises the medium pH too high. Dolomite is slower and doesn't do that, so it is a better choice. With dolomite you get a more even pH and buffering over a longer period of time.
     ​
    Just remember that different sources of dolomite will give you different reaction fractions or percentages of the limestone. The only way to really ensure you have the dolomite lime with the right residual balance and the right reactive component to it is to test it by doing the following:
     ​
    · After placing the medium in pots, irrigate with tap water avoiding any leaching to take place.
    · Reapply the water daily as needed to keep the medium moist.
    · Measure the pH at days 0, 3, 7, 10, 14, and 21.
    · Plot your results on a graph. You should see the pH stabilize after some time and see what the final pH was as well as how long it took to stabilize.
     ​
    Particle Size
    Now that we looked at limestone type, let's look at particle size. Particle size also makes a difference in how reactive the limestone is. The finer the particle size is, the more reactive the limestone is. Just so you're aware, limestone is sold in mesh sizes. The higher the mesh size, the finer the particle size.

    Hardness
    Hardness is the third important feature of limestone. A soft crystal reacts more quickly with acid than a hard crystal. Of course, there is no real way to tell if the limestone being used is soft or hard except by testing it. You have to add it to your growing medium and raise the pH to 5.3 – 6.8 and observe what happens. You can conduct a test for determining the reactivity of your limestone by adding 4 to 6 pounds of limestone per cubic yard of growing medium. If this adequately brings the pH up to 6.0, you know that the limestone is reactive, and there is little residual left once a stable pH is reached. Needing to add 8 – 12 pounds of limestone indicates the limestone is moderately reactive. Adding more than 15 pounds per cubic yard indicates an un-reactive limestone and that is not good.

    <span style="color:rgb(0,86,110);">Hydrated Limestone (A More Volatile Option)</span>​
     ​
    If you use hydrated limestone, it's another story. Hydrated limestone is known as calcium hydroxide and is a white, crystalline, slightly-soluble alkali used in the neutralization of acid soils. It reacts completely and rapidly and does not have any available residual limestone. You have to be careful with it because it will quickly shoot your pH way up.


    <span style="color:rgb(0,86,110);">Some Challenges You Should Be Aware Of</span>​
     ​
    Now you might run into a problem with adding limestone. Because adding too much limestone adds alkalinity to your growing medium which could raise the pH levels too high. In limestone, the bicarbonates settle around a pH of 6.5 to 6.7 and this is dangerously close to the pH where precipitation of iron and manganese start to happen unless they are properly chelated. If you use Sunshine #4 growing mix, you don't want to add limestone as it already has sufficient limestone in it, and adding more will increase your growing medium's pH. Be careful...if you've been using limestone in your Sunshine #4 mix you might end up with your pH going high. You might even cause your nutrient elements locking out in the growing medium. However, if you use fully chelated macro, micro and secondary nutrients, this won't happen.
    We will talk about chelates in a bit. Many of the nutrient companies don't bother with using any chelates and the ones that do usually only chelate the iron and manganese. Properly chelating nutrients is an expensive endeavor. And the lack of proper chelation is likely costing you bigger yields, and you end up having to monitor your nutrients and growing medium continually to get the right pH.

     
    <span style="color:rgb(0,86,110);">Reusing Your Growing Medium</span>​
     ​
    One thing to remember if you re-use your growing medium is that you may not get consistent yields. You should be exceptionally cautious re-using your growing medium if any of the following happens during your growing and flowering cycle: your pH is currently running wild, you're using a lot of limestone, not watering regularly, or not leaching all the nutrients out at the end of your flowering cycle. This is especially applicable to re-using sphagnum moss or coca coir. You might want to store your sphagnum or coir from one crop to the next and, while the other crop is growing, you can work with the stored medium to replenish it and get it to the right pH level for the next crop.

    <span style="color:rgb(0,86,110);">The Advantage Of Expanded Clay Pellets</span>​
     ​
    Expanded clay pellets are my personal choice for running hydroponics systems because it's easy to work with and cleans up easy for re-use. You can also re-use perlite just sift it and clean it with very hot water or use a weak solution of hydrogen peroxide and then rinse. The same can be done with expanded clay pellets. If you're using rockwool just throw it out after every crop. Though I've seen and personally re-used rockwool, it's a pain in the ass and I wouldn't do it because it has too many down sides. You're better off buying it new. Here's the bottom line: you have to be interested in your growing medium's pH and make sure it's clean if you're going to re-use it to grow your plants. Otherwise, it will be difficult for you to grow a consistently high-yielding, high quality crop. If you don't want to invest the time and money in this project, you'll be better off to go to your hydro store and get new growing medium for each crop.
     ​
    <span style="color:rgb(37,65,143);">Your Nutrients</span>​
     ​
    <span style="color:rgb(0,86,110);">Lets Take A Closer Look At This Critical Piece Of The Puzzle</span>​
     ​
    Let's have a look at how the different elements that make up your nutrients affect your pH. We mentioned this earlier at the beginning of this report. Your nutrient solution is made up of macro, micro and secondary nutrients. Macro means large and micro means little. Macro nutrients are those elements like nitrogen, phosphorus and potassium that your plants use a lot of. Micro nutrients, on the other hand, are nutrients that are only needed in very small quantities like iron, manganese, boron, copper, cobalt, molybdenum and zinc. Secondary nutrients are calcium, magnesium and sulfur and are used in smaller amounts than macro nutrients. All of these elements, macro, micro as well as secondary nutrients carry either a positive charge (cations) or a negative charge (anions) and will effect the pH of your growing medium as your plants use them up.

    In fact, most macro, micro and secondary elements can be manufactured to carry more cations or anions if a manufacturer is willing to go the extra mile and spend the additional money required to have them custom made. And of course, that's something Advanced Nutrients does. Cations include potassium, magnesium, calcium, zinc, copper, cobalt, manganese, iron and ammonium. Anions include nitrates, phosphates, sulfates, carbonates, bicarbonates. And different forms of these elements carry different amounts of anions and cations.
     ​
    <span style="color:rgb(0,86,110);">How It All Comes Together</span>​
     ​
    Your plants roots take in both anions and cations but when they do, different things occur. Like when the roots take in cations, they give off a hydrogen ions-which are acidic-and is then released into your growing medium. This makes your growing medium acidic and the pH is lowered. Now, when anions are taken in by your roots, hydroxide ions are
    released which are alkaline and that raises the pH of your growing medium. But as it goes, cations and anions actually work together.


    <span style="color:rgb(0,86,110);">Like I Mentioned Up At The Beginning...“It's A Balancing Act”</span>​
     ​
    The whole trick is to balance the cations and the anions; then you can maintain the ideal pH in your growing medium. This does take a lot of work and research, but it can be done. Why is this important? I'll let you in on the secret. When you use the cations in an ammonium based nitrogen source, it gives off acid molecules and that helps to maintain the ideal pH around the roots and in your growing medium. But when you use a mainly nitrate base nutrient, you are working with anions which gives off alkaline molecules and that raises the pH. This means you'll need to continually adjust your pH down. Why do the extra work when you can just maintain the right balance of ammonium and nitrates, cations to anions, right from the start. And I don't know for sure, but because of this imbalance of anions to cations you may have a high pH in your growing medium. And the worst part is, you aren't even aware that this harvest robbing culprit is lurking in your growing medium.

    Also, if you use a recirculating system you'll be continually adjusting your reservoir's pH in an unending cycle of pH balancing. And this directly affects the bigger yields that you could be getting.
     ​
    <span style="color:rgb(0,86,110);">Balancing Your pH</span>​
     ​
    When adjusting your reservoir's nutrients to adjust your pH. For example, potassium hydroxide (also called caustic potash) can be used to raise your pH up. Use nitric and phosphoric acid to lower your pH down. You can use nitric acid in your vegetative cycle because it will add nitrogen to your crop and phosphoric acid in your flowering cycle because it will add phosphorus. And guess what? Personally I prefer to use nitric acid in my flowering cycle because tissue samples have shown your favorite plant doesn't use a whole lot of phosphorus during flowering. In fact, in most cases nitrogen use increases.
     ​
    If you're looking for organic forms of pH down you can use citric acid to bring the pH down. This you can get at a vitamin store; just make sure that it is a really pure type of citric acid. You can even use vinegar (acetic acid) but the acetic acid varies in different vinegars so you have to be a bit more careful and watch what goes on. For this reason, citric acid is the preferred acid to use.

    <span style="color:rgb(0,86,110);">How about Using Buffers?</span>​
    Some companies promote using chemicals to buffer your hydroponics nutrients. So what is a buffer? A buffer is a chemical that helps maintain pH stability of the nutrient solution. A lot of growers aren't aware of this little known fact, but a lot of nutrient companies use magnesium, calcium and potassium carbonate or bicarbonate as their pH buffers. This is absolutely not a good idea.

    Here's why: remember that carbonates and bicarbonates are anions and add to the alkalinity of your nutrient solution and growing medium, and even though they might buffer the pH a bit, these “down and dirty” pH buffers will cause your growing mediums pH to accelerate up.
     ​
    Vitally important last and final point: Calcium, Magnesium and Potassium, using these carbonates and bicarbonates will actually diminish your crops yield potential. So check out what's in the nutrients you're using and see if they're using any magnesium carbonate, calcium carbonate, potassium carbonate, bicarbonates or worse, a combination of them. For all these reasons, Advanced Nutrients won't use them, period. Instead we invest our money in pH buffers that give you rock solid stability over your nutrient and growing mediums pH while never adding alkalinity in any way that will
    diminish the size of your harvest.
     ​
    <span style="color:rgb(0,86,110);">Adding Chelates</span>​
     ​
    OK, so lets take an in depth look at chelates. What are they, anyways? Well, chelates are complex organic molecules used to allow the micro, macro and secondary nutrients to remain available to the plant over a wider pH range. They do this by binding them to ions, and this prevents those ions from precipitating or locking out with other elements.
    You can use different chelates to lower and raise the pH level as well, depending on what you need. So the whole activity is another balancing act. Adding chelates to the mix makes it easier for the plants roots to absorb the macro, micro and secondary nutrients that it needs.
     ​
    There are several advantages of using chelates :
    · It increases availability of nutrients.
    · Mineral nutrients are prevented from forming insoluble precipitates.
    · Toxicity is reduced of some metal ions to plants.
    · It prevents nutrients from leaching.
    · The mobility of plant nutrients increases.
    · It suppresses the growth of plant pathogens.
    · When formulated correctly can help stabilize pH.
     ​
    if anyone would like to see the full article: http://growersunderground.com/pH_Manifesto.pdf

    hope you guys enjoy:smoking:
     
    • Like Like x 5
    • Winner Winner x 1
  2. my heads ganna asplode


    will read the rest later, so far so good


    thanks
     
  3. just thaught id bump it up for ppl who havnt read it yet
     
  4. Ima bump it again. Joe thanks so much for this. Even if it takes a few more reads to fully sink in. I am not sure if i can demand sticky, but i Know i can +rep you. :D


    ...and even load you one. :)
     
  5. bump for awesome thread
     
  6. This needs to be sticky!!


    I was sent this on Advanced Nutrients newsletter mailing list, this is exactly the kind of reason I signed up for it.

    Awesome stuff, I'm still trying to wrap my head around it all.
     
  7. #7 jiggaboojones, Mar 27, 2010
    Last edited by a moderator: Mar 27, 2010
    i read the original article , but this is a great effort to post this for everyone . thanx for doing this you are an asset to the community .+ rep for you. i have to spred it around rep him up peeps. he put some work in on this.
     
  8. Awesome article:hello: everyone who is serious about bigger yield should read this. I am going to make some modifications to my procedures starting with the R.O. System.

    Thanks T.B
     
  9. damn JOE that shit is EPIC!! bro. but as usual your post is quality readin' ya gotta respect a guy that lays it all out. add some humor next one so all the processing doesnt hurt no one. + for ya bro!
     
  10. Havnt read this yet but +rep for simply putting in the time. Looks like it will be an interesting read.
     
  11. Not to oversimplify but what im getting out of this is:

    There is a lot to understand about the proper medium
    + Always measure PH and PPM
    + Get a PH meter with a probe
    + Use Sunshine #4
    + Use Advanced Nutirents Products
    = Win

    Im guessing this was written by someone at Advanced Nutrients, or they are in some way affiliated with Advanced Nutrients?

    amiright?

    No matter, im convinced.

    Sunshine #4 and Adv Nutes will be my next grow.
     
  12. yes you are right, it is writen by someone at AN, and yes i use AN but please dont think i am promoting them, what this article is talking bout when it talks about AN is its telling you the superior ways that AN is made over other companies, but you may use whatever you like, it took me a long time to get this up here by copy past, then resizing then fixing all the spaces and then fixing paragraghs, took likt 3 hrs total, but more like 5 hrs cuz i dicked around. basically i posted this in referance, because i see somany ppl on here with ph problems and there is no sticky on ph that we dan easily look at. so no i didnt write this, but i do think its valuble info that should be posted here at the city:)

    thx everyone for reading this out, if ya didnt know all of it, now ya do, and if ya did know it all well now its just fresh in your mind

    have a great day all:wave:
     
  13. Thank you so much for posting the article. I enjoyed reading it and ready to do some more reading related to PH, nutrition, etc. Hope my brain can keep it up..

    Again thanks, + rep.

    Cheers
     
  14. Great reading!:hello:
     
  15. wow, bangin thread man!!! Going to take me days to learn it. MUST BE STICKY'D:cool:
     
  16. Great read dude. Gonna have to read a couple more times...but very good info def. +rep
     
  17. just thaught id bump this up one last time
     
    • Like Like x 1
  18. How is this thread not a sticky?
     
  19. Good resource and should answer a lot of questions. Now if you could only get people to actually read the sticky's before they post, that would be epic
     
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