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I don't think melting them is a good idea. First off, heating will decrease the potency of the mushroom, since the chemicals aren't very stable to begin with. Besides, if you do melt the chocolate, you'll never be able to get it all off, it's not just going to slide off perfectly. I think you're best bet is removing it carefully by hand, which will probably be easier if it's cold.
My cousins were lactose intolerant, but they could eat ice-cream and such if they took some pill (digestive enzymes?). Are you certain there's nothing your friend can take for this?
EDIT: Damn, sphinx13 got ahead of me!
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